Yes, they are legit. Of course, I'm assuming the glasses are legit in the first place and not fake glasses that have "Sample" on it.
Stuff labeled "Sample", "Sales Sample" or "SS" are items used by reps to show their accounts what the product actually is so they can order accordingly. Nothing different about the pair other than the markings. Some other items need a little more pizzaz and are called "Prototypes" but are in essence glorified sales samples. The C Six "Prototypes" are an example of those (the final version on display and in rep cases, that is). They're not different than the general release models, but they needed stronger marketing lingo than just "Sales Sample" when they were displaying in it at the Vancouver Olympics or introducing it to a range of influential bloggers.